Vertical phase separation in bulk heterojunction solar cells formed by in situ polymerization of fulleride

Vertical phase separation in bulk heterojunction solar cells formed by in situ polymerization of fulleride

Vertical phase separation of the donor and the acceptor in organic bulk heterojunction solar cells is crucial to improve the exciton dissociation and charge transport efficiencies. This is because whilst the exciton diffusion length is limited, the organic film must be thick enough to absorb sufficient light. However, it is still a challenge to control the phase separation of a binary blend in ...

Bulk Heterojunction Solar Cells — Opportunities and Challenges

P3HT:PCBM Bulk Heterojunction Solar Cells Characterization by Spectroscopic EllipsometryOptical Discs

The performance of organic solar cells based on the blends of poly(3-hexylthiophene) (P3HT) and [6,6]-phenyl C61-butyric acid methyl ester (PCBM) is strongly influenced by blend composition and thermal annealing conditions. For high-efficiency solar cells, a nanoscale interpenetrating network with crystalline order of both constituents is the desirable architecture for the photoactive layer. To...

Bulk heterojunction organic solar cells fabricated by oblique angle deposition.

Bulk heterojunction organic solar cells based on small molecules are often fabricated by the co-deposition of donor and accepter materials on substrates placed horizontally. An intimate blend of donor and acceptor molecules is the common product in as-prepared samples. Using metal phthalocyanine as the donor and fullerene as the acceptor, we tilt the substrate to deposit the active layer. Both ...

Hydrogen bonding in bulk heterojunction solar cells: A case study

Small molecules with dithieno[3,2-b;2',3'-d]thiophene as central building block and octyl cyanoacetate and octyl cyanoacetamide as different terminal building blocks have been designed and synthesized. The amide containing small molecule can form intermolecular hydrogen bonding between N-H...O = C of the amide group. The photovoltaic properties and active layer morphologies of the two molecules...